IRON AND MANGANESE SURVEY IN AQUIFERS SURROUNDING LANDFILLS IN WALLONIA (BELGIUM)

The groundwater biogeochemistry around waste disposal facilities has been widely studied since twenty years (Christensen & al, 2001). It is well known that leachates produced by water percolation through waste solid often contain high concentrations of dissolved Fe and Mn (Christensen & al, 1997). Fe(III) and Mn(IV) also enter in the composition of aquifers matrix (silts, sand, rocks). It constitutes a second reserve of electrons acceptors for further anaerobic biodegradation in aquifer environment.

Fe(II) and Mn(II) are first importance markers for characterizing and surveying aquifers contaminated with landfill leachates. However, they are not included in lists of required parameters imposed by Belgian or international environmental policiesn probably because they are not hazardous. In this study, aquifers under 4 municipal solid waste (MSW) landfills have been sampled using existing monitoring wells. It covers four different types of aquifers. For each of them, sharp increases of Fe(II) and Mn(II) concentrations are observed in some of the wells downgradient from the sites. Regional mean and maximal values for corresponding aquifers can be strongly exceeded without detecting significant anomalies of other markers.



Copyright: © IWWG International Waste Working Group
Quelle: Workshop G (Oktober 2007)
Seiten: 10
Preis inkl. MwSt.: € 10,00
Autor: Vincent Lebrun
Ali Kheffi
C. Collart
Jean-Claude Maquinay

Artikel weiterleiten In den Warenkorb legen Artikel kommentieren


Diese Fachartikel könnten Sie auch interessieren:

METAL SPECIATION IN NINE FRENCH LANDFILL LEACHATES
© IWWG International Waste Working Group (10/2007)
Several heavy metals or metalloids, that may be present in landfill leachates, are considered as priority pollutants for groundwater resources (for example lead, cadmium, nickel; OJEC, 2001). While the fate and transport of such elements are largely influenced by chemical speciation reactions, landfill risk assessments generally adopt a simplified “Kd” approach which assumes steady-state liquid-solid partition between the liquid and solid phases. Such simplification may result in a severe overestimation of long-term environmental or health impact. Speciation reactions such as precipitation or co-precipitation participate in the natural attenuation of landfill leachate and help explain why heavy metals are rarely detected in groundwater at significant distances from landfills (Christensen et al., 2001).

LEACHING BEHAVIOUR OF PAH’S IN DEMOLITION WASTE AND CONTAMINATED SOIL Premium
© IWWG International Waste Working Group (10/2007)
The investigation of pollutant transfer from waste or soil with leachate into groundwater is of fundamental importance for the assessment of risk potential posed by abandoned waste deposits or other contaminated sites. Following the German Federal Soil Protection and Contaminated Sites Ordinance (BBodSchV, 1999), a leachate forecast is required for the soil-groundwater pathway. The estimation of the pollutant transfer can be performed, among other methods, on the basis of source term strength of contaminated materials determination by laboratory tests.

EVALUATION OF ELUSION RATE OF ALKALINITY FROM BOTTOM ASH FOR A LONG TERM PERIOD
© IWWG International Waste Working Group (10/2007)
The pH in a landfill layer affects many phenomena such as dissolution/precipitation and adsorption/desorption of heavy metals, activities of microorganisms, CO2 absorption/emission etc. However, because of a lack of knowledge about the leachate characteristics after closing a landfill site, some inhabitants around a landfill site that has been constructed or is under consideration are anxious about the environmental safety of the landfill site, and often oppose the construction of a new landfill site. Therefore, it is very important to predict the pH change for a long term period for the management of a landfill site after closing. In order to predict the pH in a landfill layer, it is necessary to know the total amount of alkali and acid and their supply and consumption rates.

EVALUATION OF CAPACITANCE PROBES FOR MOISTURE MONITORING IN MUNICIPAL LANDFILLS
© IWWG International Waste Working Group (10/2007)
There exist many municipal solid waste (MSW) landfills, that have been designed using the “dry-tomb” concept, that are either closed or in their final stages of waste addition. The purpose of this design is to isolate the waste from the exterior environment thereby preventing the degradation of the landfill contents and its introduction to the surroundings. This design, however, carries with it a long-term liability. The slow decay of MSW causes a long “contaminating lifespan” during which pollutants may gradually enter the groundwater and methane production will proceed at a rate too low to be utilized economically thus contributing to greenhouse gas emissions. The length of this lifespan cannot be known exactly, but modelling suggests times of a hundred years or more after closure are not unreasonable. (Rowe, 2001)

MODELING OF TRANSPORT AND GEOCHEMICAL PROCESSES BETWEEN LANDFILL LEACHATE AND A SATURATED BARRIER SYSTEM
© IWWG International Waste Working Group (10/2007)
Landfill leachate is a dangerous and polluting solution formed by a very complex sequence of physical, chemical and biological processes modifying the rainwater that percolates through waste (Bogner et al.,1996). Migration of the pollutants from the waste material into the percolating water is another important phenomenon requiring attention (Mora-Naranjo et al., 2004). The resulting leachate is a solution containing dissolved organic matter, inorganic macrocomponents, heavy metals and xenobiotic organic compounds and is characterized by reducing redox state (Christensen et al., 2001). Migration is a long-term and continuous process and the leachate may evolve and pollute the surrounding environment for hundred of years (Ustohalova et al., 2006).

Name:

Passwort:

 Angemeldet bleiben

Passwort vergessen?